The use of inorganic catalysts is well described as a method to produce
valuable chemicals in the petroleum industry; however, widespread adoption
of these techniques for corn-based feed streams has not occurred. The
reason for this lack of acceptance is due to the varied nature of a
biobased feed stream. This feed stream produces a product that contains
multiple compounds. This mixture of compounds in the product stream
causes a separation challenge. The difficulty separating these chemicals
is compounded by the fact that they have very similar properties. It
is therefore cost prohibitive to use traditional techniques to purify
these compounds. This hurdle has resulted in very little research being
directed towards inorganic catalysis of corn-based feed streams. These
concerns have led researchers at Michigan State University in conjunction
with the National Corn Growers Association to investigate a separation
process known as reactive distillation.
Reactive distillation is a technique in which a mixed chemical stream
is treated with a reactive chemical in the presence of a catalyst. This
results in a mixture of chemicals that can be easily separated, saving
both energy and plant design costs. It is anticipated that this technology
will allow the application of traditional catalysts to non-traditional
corn-derived feed streams. Acid esters are compounds that could be produced
via this method. The current market for these chemicals is around $3
billion a year. Development of this technology will build a large and
valuable market for corn.